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Ethene () polymerises to polyethylene according to the simplified equation n\ \mathrm{C_2H_4} \rightarrow \text{(C_2H_4)}_n. If of ethene at STP is completely polymerised, calculate the mass of polyethylene formed (molar mass of the repeating unit \mathrm{C_2H_4} = 28\ \text{g mol^{-1}}). Assume the polymer contains the same number of repeating units as moles of ethene reacted.

medium 3 marks Class 10 · Science · Carbon and its Compounds
Answer
6.25 g of polyethylene

The correct answer is 6.25 g of polyethylene — State the final mass.

Step-by-step solution

  1. At STP, 1 mol of any gas occupies .
  2. Moles of ethene = .
  3. Each mole of ethene becomes one mole of the repeating unit in the polymer, so moles of repeating units = 0.2232 mol.
  4. Mass of polymer = moles molar mass of the repeating unit = .
  5. State the final mass.
Common mistake: Using the molar volume of liquids instead of gases, or forgetting that the mass of polymer equals the combined mass of the monomer units.

Concept tested: Polymerisation and molar calculations

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