Lesson eLearning

1‑Phenylethanol () is oxidised with pyridinium chlorochromate (PCC). Identify the major product and provide its common and IUPAC names.

hard 3 marks Class 12 · Chemistry · Alcohols Phenols and Ethers
Answer
Acetophenone – 1‑phenylethanone

The correct answer is Acetophenone – 1‑phenylethanone — Step 5: Verify that no over‑oxidation occurs because PCC is a mild oxidant.

Step-by-step solution

  1. Step 1: PCC oxidises primary and secondary alcohols to aldehydes and ketones respectively.
  2. Step 2: 1‑Phenylethanol is a secondary alcohol; PCC will oxidise it to a ketone.
  3. Step 3: The ketone obtained is , which is acetophenone.
  4. Step 4: The common name is acetophenone; the IUPAC name is 1‑phenylethanone.
  5. Step 5: Verify that no over‑oxidation occurs because PCC is a mild oxidant.
Common mistake: Confusing the product with an aldehyde

Concept tested: Oxidation of secondary alcohols – PCC

Published · Last updated · How this solution was prepared and checked

← All Alcohols Phenols and Ethers questions