A 4.0 g sample of acetic acid is esterified with excess ethanol in the presence of concentrated H₂SO₄ to give ethyl acetate. Calculate the theoretical mass of ethyl acetate that can be formed. (Molar mass CH₃COOH = 60.05 g mol⁻¹, CH₃COOC₂H₅ = 88.11 g mol⁻¹.)
Answer
5.87 g
The correct answer is 5.87 g — Theoretical mass of ethyl acetate that can be formed is 5.87 g.
Step-by-step solution
- Determine moles of acetic acid: .
- The esterification stoichiometry is 1:1: 1 mol acetic acid → 1 mol ethyl acetate.
- Hence moles of ethyl acetate produced = 0.0666 mol.
- Calculate mass of ethyl acetate: .
- Theoretical mass of ethyl acetate that can be formed is 5.87 g.
Common mistake: Using the wrong limiting reagent or the wrong molar mass
Concept tested: Fischer esterification yield calculation
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