Lesson eLearning

Which of the following compounds is the most basic at 25°C in aqueous solution?

medium MCQ 2 marks Class 12 · Chemistry · Amines
  1. aniline
  2. diethylamine
  3. 1-methylpyrrolidine
  4. pyridine
Answer
diethylamine

The correct answer is diethylamine — Conclude that diethylamine is the most basic compound.

Step-by-step solution

  1. Write the base dissociation constants for the options: aniline (Kb≈5.9×10⁻¹⁰), diethylamine (Kb≈5.6×10⁻⁴), 1‑methylpyrrolidine (Kb≈5×10⁻⁴), pyridine (Kb≈1.7×10⁻⁹).
  2. Compare the Kb values; the larger the Kb, the stronger the base.
  3. Identify the largest Kb, which belongs to diethylamine.
  4. Conclude that diethylamine is the most basic compound.
Common mistake: Confusing pKb with Kb or ignoring the effect of resonance

Concept tested: Relative basicity of amines

Published · How this solution was prepared and checked

← All Amines questions