Which of the following compounds is the most basic at 25°C in aqueous solution?
Answer
diethylamine
The correct answer is diethylamine — Conclude that diethylamine is the most basic compound.
Step-by-step solution
- Write the base dissociation constants for the options: aniline (Kb≈5.9×10⁻¹⁰), diethylamine (Kb≈5.6×10⁻⁴), 1‑methylpyrrolidine (Kb≈5×10⁻⁴), pyridine (Kb≈1.7×10⁻⁹).
- Compare the Kb values; the larger the Kb, the stronger the base.
- Identify the largest Kb, which belongs to diethylamine.
- Conclude that diethylamine is the most basic compound.
Common mistake: Confusing pKb with Kb or ignoring the effect of resonance
Concept tested: Relative basicity of amines
Published · How this solution was prepared and checked
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