Which oxidation state is most commonly exhibited by the lanthanide elements in their aqueous compounds?
Answer
+3
The correct answer is +3 — Therefore the oxidation state most frequently observed is +3.
Step-by-step solution
- Recall that lanthanides have the electronic configuration where n = 0 to 14.
- In aqueous solution the 6s electrons are readily removed, and the 4f electrons are poorly shielded, making the +3 state stable.
- Examine experimental data: the majority of lanthanide salts (e.g., chlorides, nitrates) contain the ion .
- Therefore the oxidation state most frequently observed is +3.
Common mistake: Assuming +4 is the most common oxidation state for all lanthanides
Concept tested: common oxidation state of lanthanides
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