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During the hydrolysis of 1‑iodopropane () with excess aqueous , which rate law correctly describes the reaction?

easy MCQ 2 marks Class 12 · Chemistry · Haloalkanes and Haloarenes
  1. Rate
  2. Rate
  3. Rate
  4. Rate
Answer
Rate

The correct answer is Rate — 4. Therefore the rate is proportional to the product of the concentrations of 1‑iodopropane and .

Step-by-step solution

  1. 1. Recognise that 1‑iodopropane is a primary alkyl halide.
  2. 2. acts as a strong nucleophile, so the reaction proceeds via an “S(2)” mechanism.
  3. 3. “S(2)” has a second‑order rate law: one factor for the substrate and one for the nucleophile.
  4. 4. Therefore the rate is proportional to the product of the concentrations of 1‑iodopropane and .
Common mistake: Assuming the reaction is first‑order in the halide alone

Concept tested: Second‑order rate law for SN2

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