During the hydrolysis of 1‑iodopropane () with excess aqueous , which rate law correctly describes the reaction?
Answer
Rate
The correct answer is Rate — 4. Therefore the rate is proportional to the product of the concentrations of 1‑iodopropane and .
Step-by-step solution
- 1. Recognise that 1‑iodopropane is a primary alkyl halide.
- 2. acts as a strong nucleophile, so the reaction proceeds via an “S(2)” mechanism.
- 3. “S(2)” has a second‑order rate law: one factor for the substrate and one for the nucleophile.
- 4. Therefore the rate is proportional to the product of the concentrations of 1‑iodopropane and .
Common mistake: Assuming the reaction is first‑order in the halide alone
Concept tested: Second‑order rate law for SN2
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