In a laboratory, 90 mL of 0.05 M HCl is mixed with 120 mL of 0.03 M NaOH. Write the balanced chemical equation and calculate the pH of the resulting solution.
Answer
2.37
The correct answer is 2.37 — Compute pH: pH = –log₁₀(0.0042857) = 2.368 ≈ 2.37.
Step-by-step solution
- Write the neutralisation reaction: .
- Calculate moles of acid: 0.090 L × 0.05 mol L⁻¹ = 0.0045 mol.
- Calculate moles of base: 0.120 L × 0.03 mol L⁻¹ = 0.0036 mol.
- Neutralise the base with an equal amount of acid: 0.0036 mol of H⁺ reacts with 0.0036 mol of OH⁻, forming 0.0036 mol of water.
- Remaining excess acid: 0.0045 mol – 0.0036 mol = 0.0009 mol H⁺.
- Total volume of solution: 90 mL + 120 mL = 210 mL = 0.210 L.
- Concentration of excess H⁺: 0.0009 mol ÷ 0.210 L = 0.0042857 M.
- Compute pH: pH = –log₁₀(0.0042857) = 2.368 ≈ 2.37.
Common mistake: using incorrect volume conversion or neglecting excess reactant
Concept tested: Stoichiometry & pH calculation
Published · How this solution was prepared and checked
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